The nature of the catalytically active species in olefin dioxygenation with PhI(OAc)2: metal or proton?
Evidence for the protiocatalytic nature of the diacetoxylation of alkenes using PhI(OAc)2 as oxidant is presented. Systematic studies into the catalytic activity in the presence of proton-trapping and metal-complexing agents indicate that protons act as catalysts in the reaction. Using triflic acid...
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| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
February 16, 2011
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| In: |
Journal of the American Chemical Society
Year: 2011, Volume: 133, Issue: 10, Pages: 3658-3667 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/ja110805b |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ja110805b
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| Author Notes: | Yan-Biao Kang and Lutz H. Gade |