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Catalysts by the meter: rapid screening approach of N-heterocyclic carbene ligand based catalysts

Here, we demonstrate a versatile screening platform for NHC ligand based catalysts by coating fused-silica micro capillaries with a bonded 1,3-bismesityl-2-imidazolidinylidene ligand. Such micro capillaries can be efficiently converted into (pre)-catalysts from various organometallic precursors by s...

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Bibliographische Detailangaben
Hauptverfasser: Lang, Carolin (VerfasserIn) , Gaertner, Ute (VerfasserIn) , Trapp, Oliver (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2011
In: Chemical communications
Year: 2011, Jahrgang: 47, Heft: 1, Pages: 391-393
ISSN:1364-548X
DOI:10.1039/C0CC02306J
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C0CC02306J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2011/cc/c0cc02306j
Volltext
Verfasserangaben:Carolin Lang, Ute Gärtner and Oliver Trapp
Beschreibung
Zusammenfassung:Here, we demonstrate a versatile screening platform for NHC ligand based catalysts by coating fused-silica micro capillaries with a bonded 1,3-bismesityl-2-imidazolidinylidene ligand. Such micro capillaries can be efficiently converted into (pre)-catalysts from various organometallic precursors by solid-phase chemistry techniques and can be quantitatively screened using on-column reaction chromatography.
Beschreibung:First published: 08 Sep 2010
Gesehen am 12.07.2022
Beschreibung:Online Resource
ISSN:1364-548X
DOI:10.1039/C0CC02306J

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