(Acetonitrile-κN)(2-(diphenylphosphanyl)ethanamine-κ2N,P)((1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl)iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6·C4H8O, the metal ion is coordinated by the η5-Cp* ring as well as the P and N atoms of the chelating 2-(diphenylphosphino)ethylamine ligand and an additional acetonitrile molecule in a piano-chair conformation. The PF6− ani...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2011
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| In: |
Acta crystallographica. Section E, Crystallographic communications
Year: 2011, Volume: 67, Issue: 8, Pages: m1135, sup1-sup2 |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/S1600536811028832 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1107/S1600536811028832 Verlag, kostenfrei, Volltext: https://scripts.iucr.org/cgi-bin/paper?go2017 |
| Author Notes: | Kajin Lee, Frank Rominger and Michael Limbach |
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| 246 | 3 | 3 | |a (Acetonitrile-[kappa]N)(2-(diphenylphosphanyl)ethanamine-[kappa]2N,P)((1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl)iron(II) hexafluoridophosphate tetrahydrofuran monosolvate |
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| 500 | |a Im Titel ist 2 bei "ethanamine-κ" hochgestellt, die Ausdrücke "2-(diphenylphosphanyl)ethanamine-κ2N,P" und "(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl" stehen jeweils in eckiger Klammer | ||
| 500 | |a Gesehen am 08.08.2022 | ||
| 520 | |a In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6·C4H8O, the metal ion is coordinated by the η5-Cp* ring as well as the P and N atoms of the chelating 2-(diphenylphosphino)ethylamine ligand and an additional acetonitrile molecule in a piano-chair conformation. The PF6− anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7). | ||
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