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Gold catalysis: domino reaction of en-diynes to highly substituted phenols

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By Sonogashira coupling of 1,7-heptadiynes and 1,8-octadiynes with 2-iodoallyl alcohols, various substrates that bear a 2-alkynylallyl alcohol moiety tethered to an additional alkyne were prepared in one step. Subjection to nitrogen acyclic carbene (NAC)/gold(I) catalysts delivered highly substitute...

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Bibliographic Details
Main Authors: Hashmi, A. Stephen K. (Author) , Häffner, Tobias (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 07 June 2011
In: Chemistry - a European journal
Year: 2011, Volume: 17, Issue: 29, Pages: 8195-8201
ISSN:1521-3765
DOI:10.1002/chem.201100305
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201100305
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201100305
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Author Notes:A. Stephen K. Hashmi, Tobias Häffner, Matthias Rudolph, and Frank Rominger
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