Cyclization of 2-alkynylallyl alcohols to highly substituted furans by gold(I)-carbene complexes

Various 2-alkynylallyl alcohols were synthesized by a generally applicable Sonogashira coupling protocol. Subsequent gold-catalyzed transformation was investigated. The use of AuI catalysts bearing carbene ligands, of either the N-heterocyclic carbene or nitrogen acyclic carbene type, delivered the...

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Main Authors: Hashmi, A. Stephen K. (Author) , Häffner, Tobias (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: February 2011
In: European journal of organic chemistry
Year: 2010, Issue: 4, Pages: 667-671
ISSN:1099-0690
DOI:10.1002/ejoc.201001479
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201001479
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201001479
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Author Notes:A. Stephen K. Hashmi, Tobias Häffner, Matthias Rudolph, and Frank Rominger