Gold-catalyzed cyclizations: a comparative study of ortho,ortho′-substituted KITPHOS monophosphines with their biaryl monophosphine counterpart SPHOS
Electrophilic gold(I) triflimide (trifluoromethanesulfonimide) complexes of electron-rich ortho,ortho′-disubstituted KITPHOS (11-dicyclohexylphosphino-12-phenyl-9,10-ethenoanthracene) monophosphines are efficient catalysts for intramolecular cycloisomerizations that afford phenols, 3-acylindenes and...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 28, 2011
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| In: |
Advanced synthesis & catalysis
Year: 2011, Volume: 353, Issue: 5, Pages: 749-759 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000879 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000879 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000879 |
| Author Notes: | A. Stephen K. Hashmi, Annette Loos, Simon Doherty, Julian G. Knight, Katharine J. Robson, and Frank Rominger |