Evidence for boron incorporation into the serpentine crystal structure
Serpentinite mud volcanoes from the Mariana forearc comprise B-rich mantle wedge peridotites serpentinized by slab fluids. The major component of these rocks are serpentine group minerals [Mg 3 Si 2 O 5 (OH) 4 ], showing highly variable textural and geochemical features. Micro-Raman spectroscopy rev...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2011
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| In: |
American mineralogist
Year: 2011, Volume: 96, Issue: 7, Pages: 1112-1119 |
| ISSN: | 1945-3027 |
| DOI: | 10.2138/am.2011.3709 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.2138/am.2011.3709 Verlag, lizenzpflichtig, Volltext: https://www.degruyterbrill.com/document/doi/10.2138/am.2011.3709/html 
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| Author Notes: | Sonja Pabst, Thomas Zack, Ivan P. Savov, Thomas Ludwig, Detlef Rost, Edward P. Vicenzi |
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| 520 | |a Serpentinite mud volcanoes from the Mariana forearc comprise B-rich mantle wedge peridotites serpentinized by slab fluids. The major component of these rocks are serpentine group minerals [Mg 3 Si 2 O 5 (OH) 4 ], showing highly variable textural and geochemical features. Micro-Raman spectroscopy reveals that the serpentine minerals are well-crystallized lizardite and chrysotile. In situ SIMS spot analyses and element mapping via ToF-SIMS show that B is evenly distributed across serpentine grains, suggesting that serpentine, both lizardite and chrysotile in different textural regions, can host significant amounts of B (up to -200 μg/g) into its crystal structure. As such structurally bound B can only be released during recrystallization or serpentine breakdown, our results have implications for modeling of the efficiency of cross-arc fluid mobile element recycling in subduction zones and stress the importance of the hydrated forearc mantle as a reservoir for fluid mobile elements. | ||
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