Gold catalysis: 1,3-oxazines by cyclisation of allene amides

A series of allene amides was prepared and their gold-catalysed cyclisation was investigated. The formation of six-membered rings, 1,3-oxazines, was observed. Dihydropyrroles originating from intramolecular hydroamination of the distal CC double bonds of the allenes were minor side products. Mechan...

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Bibliographic Details
Main Authors: Hashmi, A. Stephen K. (Author) , Schuster, Andreas M. (Author) , Litters, Sebastian (Author) , Rominger, Frank (Author) , Pernpointner, Markus (Author)
Format: Article (Journal)
Language:English
Published: 12 April 2011
In: Chemistry - a European journal
Year: 2011, Volume: 17, Issue: 20, Pages: 5661-5667
ISSN:1521-3765
DOI:10.1002/chem.201100132
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201100132
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201100132
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Author Notes:A. Stephen K. Hashmi, Andreas M. Schuster, Sebastian Litters, Frank Rominger, and Markus Pernpointner