Gold-catalyzed cyclization of nonterminal propargylic amides to substituted alkylideneoxazolines and -oxazines

The substrate scope of the gold-catalyzed cyclization of nonterminal propargylic amides to oxazolines and oxazines was investigated. Sixteen alkyl-substituted and 35 aryl-substited substrates were prepared by a very variable route from trimethylsilyl-(TMS-)protected, nonterminal propargylamines. Ste...

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Bibliographic Details
Main Authors: Hashmi, A. Stephen K. (Author) , Schuster, Andreas M. (Author) , Schmuck, Martin (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 22 June 2011
In: European journal of organic chemistry
Year: 2011, Issue: 24, Pages: 4595-4602
ISSN:1099-0690
DOI:10.1002/ejoc.201100342
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201100342
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201100342
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Author Notes:A. Stephen K. Hashmi, Andreas M. Schuster, Martin Schmuck, and Frank Rominger