Synthesis of 5-Halo-4H-1,3-oxazine-6-amines by a copper-mediated domino reaction
Three become one! In one copper-mediated step, three simple components, including a propargylcarboxamide, a protected amine, and a source of chloride, assemble to give highly functionalized oxazines, which are interesting building blocks for the synthesis of other aminooxazine derivatives (see schem...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
13 April 2011
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| In: |
Chemistry - a European journal
Year: 2011, Jahrgang: 17, Heft: 20, Pages: 5511-5515 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201100423 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201100423 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201100423 
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| Verfasserangaben: | A. Stephen K. Hashmi, Andreas M. Schuster, Marc Zimmer, and Frank Rominger |
MARC
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| 520 | |a Three become one! In one copper-mediated step, three simple components, including a propargylcarboxamide, a protected amine, and a source of chloride, assemble to give highly functionalized oxazines, which are interesting building blocks for the synthesis of other aminooxazine derivatives (see scheme; R1=range of aryl or alkyl groups, R2=alkyl, EWG=electron-withdrawing group). | ||
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