Synthesis, structure and reactions of an amidinate stabilised trigallane
The neutral trigallane R3Ga3I2 was obtained in high yields by reaction of “GaI” with the moderately sterically demanding lithium N,N′-dicyclohexylneopentylamidinate. Its chemical reactions with N-lithio-2-propanimine, sodium superhydride and elemental iodine were investigated. RI-DFT calculations ha...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2011
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| In: |
Dalton transactions
Year: 2011, Jahrgang: 40, Heft: 20, Pages: 5591-5598 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C1DT10209E |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C1DT10209E Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2011/dt/c1dt10209e 
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| Verfasserangaben: | Gerald Linti and Thomas Zessin |
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| 520 | |a The neutral trigallane R3Ga3I2 was obtained in high yields by reaction of “GaI” with the moderately sterically demanding lithium N,N′-dicyclohexylneopentylamidinate. Its chemical reactions with N-lithio-2-propanimine, sodium superhydride and elemental iodine were investigated. RI-DFT calculations have been performed to confirm the bonding situation. All compounds are characterised by crystal structure analysis and NMR-spectroscopy. | ||
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