On-surface assembly of hydrogen- and halogen-bonded supramolecular graphyne-like networks
Demonstrated here is a supramolecular approach to fabricate highly ordered monolayered hydrogen- and halogen-bonded graphyne-like two-dimensional (2D) materials from triethynyltriazine derivatives on Au(111) and Ag(111). The 2D networks are stabilized by N⋅⋅⋅H−C(sp) bonds and N⋅⋅⋅Br−C(sp) bonds to t...
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| Hauptverfasser: | , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2020
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| In: |
Angewandte Chemie. International edition
Year: 2020, Jahrgang: 59, Heft: 24, Pages: 9549-9555 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201916708 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201916708 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201916708 
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| Verfasserangaben: | Zechao Yang, Lukas Fromm, Tim Sander, Julian Gebhardt, Tobias A. Schaub, Andreas Görling, Milan Kivala, and Sabine Maier |
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| 245 | 1 | 0 | |a On-surface assembly of hydrogen- and halogen-bonded supramolecular graphyne-like networks |c Zechao Yang, Lukas Fromm, Tim Sander, Julian Gebhardt, Tobias A. Schaub, Andreas Görling, Milan Kivala, and Sabine Maier |
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| 500 | |a Gesehen am 26.09.2022 | ||
| 520 | |a Demonstrated here is a supramolecular approach to fabricate highly ordered monolayered hydrogen- and halogen-bonded graphyne-like two-dimensional (2D) materials from triethynyltriazine derivatives on Au(111) and Ag(111). The 2D networks are stabilized by N⋅⋅⋅H−C(sp) bonds and N⋅⋅⋅Br−C(sp) bonds to the triazine core. The structural properties and the binding energies of the supramolecular graphynes have been investigated by scanning tunneling microscopy in combination with density-functional theory calculations. It is revealed that the N⋅⋅⋅Br−C(sp) bonds lead to significantly stronger bonded networks compared to the hydrogen-bonded networks. A systematic analysis of the binding energies of triethynyltriazine and triethynylbenzene derivatives further demonstrates that the X3-synthon, which is commonly observed for bromobenzene derivatives, is weaker than the X6-synthon for our bromotriethynyl derivatives. | ||
| 650 | 4 | |a graphyne | |
| 650 | 4 | |a halogen bonds | |
| 650 | 4 | |a hydrogen bonds | |
| 650 | 4 | |a nanostructures | |
| 650 | 4 | |a self-assembly | |
| 650 | 4 | |a surface chemistry | |
| 700 | 1 | |a Fromm, Lukas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Sander, Tim |e VerfasserIn |4 aut | |
| 700 | 1 | |a Gebhardt, Julian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Schaub, Tobias A. |e VerfasserIn |0 (DE-588)1206896787 |0 (DE-627)1693136155 |4 aut | |
| 700 | 1 | |a Görling, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kivala, Milan |e VerfasserIn |0 (DE-588)120357231X |0 (DE-627)1688558489 |4 aut | |
| 700 | 1 | |a Maier, Sabine |e VerfasserIn |4 aut | |
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