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Enantioselective syntheses of tetrahydroquinolines based on iridium-catalyzed allylic substitutions: total syntheses of (+)-angustureine and (-)-cuspareine

A protecting-group-free two-step approach for the preparation of tetrahydroquinolines has been developed. The procedure involves a highly regio- and enantioselective intermolecular iridium-catalyzed allylic amination followed by one-pot hydroboration and intramolecular Suzuki-Miyaura cross-coupling....

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Hauptverfasser: Satyanarayana, Gedu (VerfasserIn) , Pflästerer, Daniel (VerfasserIn) , Helmchen, Günter (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 28 September 2011
In: European journal of organic chemistry
Year: 2011, Heft: 34, Pages: 6877-6886
ISSN:1099-0690
DOI:10.1002/ejoc.201100981
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201100981
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201100981
Volltext
Verfasserangaben:Gedu Satyanarayana, Daniel Pflästerer, and Günter Helmchen

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650 4 |a Alkaloids 
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