A set of olefin metathesis catalysts with extraordinary stickiness to silica
We report on a series of six new pyridinealkoxide-bridged first and second generation ruthenium carbenes with similar or even higher activity in ring-opening metathesis polymerization (ROMP), cross metathesis (CM), and ring closing metathesis (RCM) reactions than state-of-the-art catalysts. The new...
Gespeichert in:
| Hauptverfasser: | , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
23 June 2011
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| In: |
ACS catalysis
Year: 2011, Jahrgang: 1, Heft: 8, Pages: 872-876 |
| ISSN: | 2155-5435 |
| DOI: | 10.1021/cs2002109 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/cs2002109
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| Verfasserangaben: | Jörg A. Schachner, José Cabrera, Robin Padilla, Christoph Fischer, Paul A. van der Schaaf, Roger Pretot, Frank Rominger, and Michael Limbach |
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| 245 | 1 | 2 | |a A set of olefin metathesis catalysts with extraordinary stickiness to silica |c Jörg A. Schachner, José Cabrera, Robin Padilla, Christoph Fischer, Paul A. van der Schaaf, Roger Pretot, Frank Rominger, and Michael Limbach |
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| 520 | |a We report on a series of six new pyridinealkoxide-bridged first and second generation ruthenium carbenes with similar or even higher activity in ring-opening metathesis polymerization (ROMP), cross metathesis (CM), and ring closing metathesis (RCM) reactions than state-of-the-art catalysts. The new precatalysts show an extraordinarily high stickiness to commercially available silica, which significantly enhances their adsorptive separation from unprocessed reaction mixtures. | ||
| 700 | 1 | |a Cabrera, José |e VerfasserIn |4 aut | |
| 700 | 1 | |a Padilla, Robin |e VerfasserIn |4 aut | |
| 700 | 1 | |a Fischer, Christoph |e VerfasserIn |4 aut | |
| 700 | 1 | |a van der Schaaf, Paul A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Pretot, Roger |e VerfasserIn |4 aut | |
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| 700 | 1 | |a Limbach, Michael |e VerfasserIn |4 aut | |
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