Synthesis and characterization of a doubly base-stabilized B3H6+ analogue
The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center b...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
16 September 2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Volume: 50, Issue: 44, Pages: 10444-10447 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201104834 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201104834 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201104834 |
| Author Notes: | Nikola Schulenberg, Hubert Wadepohl, and Hans-Jörg Himmel |
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| 246 | 3 | 3 | |a Synthesis and characterization of a doubly base-stabilized B 3 H 6 + analogue |
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| 520 | |a The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center bonding and σ-aromatic character. | ||
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