Komplexierung von 1,3-Dihydro-1,3-diborapentafulven-Derivaten mit Fe(CO)3-Fragmenten: Synthesen, Kristall- und Elektronenstruktur von μ-(η4:η5-1,3-Dihydro-1,3-diborapentafulven)-bis (tricarbonyleisen)-Komplexen
Complexation of 1,3-Dihydro-1,3-diborapentafulvene Derivatives with Fe(CO)3 Fragments: Syntheses, Crystal and Electronic Structure of μ-(η4: η5-1,3-Dihydro-1,3-diborapentafulvene)-bis(tricarbonyliron) Complexes Reactions of the 1,3-diborapentafulvene derivatives 1a-c with (CO)3Fe(C8H14)2 lead to the...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Deutsch |
| Veröffentlicht: |
1991
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| In: |
Chemische Berichte - recueil
Year: 1991, Jahrgang: 124, Heft: 7, Pages: 1505-1509 |
| ISSN: | 3052-8933 |
| DOI: | 10.1002/cber.19911240704 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cber.19911240704 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cber.19911240704 
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| Verfasserangaben: | Achim Feßenbecker, Markus Enders, Hans Pritzkow, Walter Siebert, Isabella Hyla-Kryspin und Rolf Gleiter |
MARC
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| 245 | 1 | 0 | |a Komplexierung von 1,3-Dihydro-1,3-diborapentafulven-Derivaten mit Fe(CO)3-Fragmenten |b Synthesen, Kristall- und Elektronenstruktur von μ-(η4:η5-1,3-Dihydro-1,3-diborapentafulven)-bis (tricarbonyleisen)-Komplexen |c Achim Feßenbecker, Markus Enders, Hans Pritzkow, Walter Siebert, Isabella Hyla-Kryspin und Rolf Gleiter |
| 246 | 3 | 0 | |a mu eta eta |
| 246 | 3 | 3 | |a Komplexierung von eins, drei-Dihydro-eins, drei-diborapentafulven-Derivaten mit Fe(CO) 3 - Fragmenten |
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| 500 | |a Die Zahl "3" im Ausdruck "Fe(CO)3" ist tiefgestellt | ||
| 500 | |a First published: Juli 1991 | ||
| 500 | |a Gesehen am 09.11.2022 | ||
| 520 | |a Complexation of 1,3-Dihydro-1,3-diborapentafulvene Derivatives with Fe(CO)3 Fragments: Syntheses, Crystal and Electronic Structure of μ-(η4: η5-1,3-Dihydro-1,3-diborapentafulvene)-bis(tricarbonyliron) Complexes Reactions of the 1,3-diborapentafulvene derivatives 1a-c with (CO)3Fe(C8H14)2 lead to the violet dinuclear complexes 3a-c, which possess a slipped triple-decker structure. The X-ray structure analyses of 3b,c reveal that one Fe(CO)3 group is pentahapto-coordinated to the 1,3-diborole frame of C2B2C=C, whereas the other interacts with the Y-shaped B2C=C unit. The latter resembles the interaction of Fe(CO)3 with trimethylenemethane. An MO calculation indicates that the formation of 3 occurs by distortion of 1 · Fe(CO)3; the slippage of Fe(CO)3 from η5 to η4 bonding is followed by η5 coordination of the second Fe(CO)3 group. | ||
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| 650 | 4 | |a 3-Diborapentafulvene | |
| 650 | 4 | |a ab initio | |
| 650 | 4 | |a Calculations | |
| 650 | 4 | |a EH | |
| 650 | 4 | |a Iron tricarbonyl complexes | |
| 650 | 4 | |a Slipped triple-decker | |
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| 773 | 0 | 8 | |i Enthalten in |t Chemische Berichte - recueil |d Weinheim : Wiley-VCH Verl., 1997 |g 124(1991), 7, Seite 1505-1509 |h Online-Ressource |w (DE-627)508725550 |w (DE-600)2224932-1 |w (DE-576)255533470 |x 3052-8933 |7 nnas |a Komplexierung von 1,3-Dihydro-1,3-diborapentafulven-Derivaten mit Fe(CO)3-Fragmenten Synthesen, Kristall- und Elektronenstruktur von μ-(η4:η5-1,3-Dihydro-1,3-diborapentafulven)-bis (tricarbonyleisen)-Komplexen |
| 773 | 1 | 8 | |g volume:124 |g year:1991 |g number:7 |g pages:1505-1509 |g extent:5 |a Komplexierung von 1,3-Dihydro-1,3-diborapentafulven-Derivaten mit Fe(CO)3-Fragmenten Synthesen, Kristall- und Elektronenstruktur von μ-(η4:η5-1,3-Dihydro-1,3-diborapentafulven)-bis (tricarbonyleisen)-Komplexen |
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