Hydrocobaltierung von 1,3-Dihydro-1,3-diborafulven-Derivaten HCo(CO)4: Herrn Prof. Dr. Paul Binger zum 60. Geburtstag gewidmet = Hydrocobaltation of 1,3-dihydro-1,3-diborafulvene derivatives with HCo(CO)4
(3) Hydrocobaltation reactions of 1,3-dibora-4,5-benzofulvene (2) and 1,3-dibora[5]radialene with HCo(CO) 4 lead to the complexes tricarbonyl-(η 5 -4,5-benzo-2-isopropyl-1,3-dimethyl- 2,3-dihydro-1,3-diborolyl)cobalt (4) and tricarbonyl-(η 5 -isopropenyl-2,5-diisopropyl-1,3-dimethyl-1,3-dihydro-1,3-...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Deutsch |
| Veröffentlicht: |
1992
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| In: |
Zeitschrift für Naturforschung. B, a journal of chemical sciences
Year: 1992, Jahrgang: 47, Heft: 1, Pages: 35-38 |
| ISSN: | 1865-7117 |
| DOI: | 10.1515/znb-1992-0110 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1515/znb-1992-0110 Verlag, lizenzpflichtig, Volltext: https://www.degruyterbrill.com/document/doi/10.1515/znb-1992-0110/html 
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| Verfasserangaben: | Zsuzsa Nagy-Magos, Markus Enders, Hans Pritzkow und Walter Siebert |
MARC
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| 245 | 1 | 0 | |a Hydrocobaltierung von 1,3-Dihydro-1,3-diborafulven-Derivaten HCo(CO)4 |b Herrn Prof. Dr. Paul Binger zum 60. Geburtstag gewidmet = Hydrocobaltation of 1,3-dihydro-1,3-diborafulvene derivatives with HCo(CO)4 |c Zsuzsa Nagy-Magos, Markus Enders, Hans Pritzkow und Walter Siebert |
| 246 | 3 | 1 | |a Hydrocobaltation of 1,3-dihydro-1,3-diborafulvene derivatives with HCo(CO)4 |
| 246 | 3 | 3 | |a Hydrocobaltierung von 1,3-Dihydro-1,3-diborafulven-Derivaten HCo(CO) 4 |
| 264 | 1 | |c 1992 | |
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| 500 | |a Im Titel ist "4" im Ausdruck "HCo(CO)4" tiefgestellt | ||
| 500 | |a Gesehen am 09.11.2022 | ||
| 520 | |a (3) Hydrocobaltation reactions of 1,3-dibora-4,5-benzofulvene (2) and 1,3-dibora[5]radialene with HCo(CO) 4 lead to the complexes tricarbonyl-(η 5 -4,5-benzo-2-isopropyl-1,3-dimethyl- 2,3-dihydro-1,3-diborolyl)cobalt (4) and tricarbonyl-(η 5 -isopropenyl-2,5-diisopropyl-1,3-dimethyl-1,3-dihydro-1,3-diborolyl)cobalt (5) in 24% and 5% yield, respectively. The constitution of 4 and 5 follows from the spectroscopic data, and is proven by an X-ray structure analysis of 4. The formation of 5 is accompanied by a 1,5-hydrogen shift in the 1.3-dibora[5]radialene (3). | ||
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