Cover Image

Optimising BTP ligands by tuning their basicity

A novel approach for the optimisation of extractants for the actinide(III)/lanthanide(III) separation is presented. Two BTP ligands are synthesised carrying OMe or Cl moieties on the pyridine ring, thus altering the electronic structure of the aromatic system. The influence of functionalisation on t...

Full description

Saved in:
Bibliographic Details
Main Authors: Trumm, Sascha (Author) , Wipff, G. (Author) , Geist, Andreas (Author) , Panak, Petra (Author) , Fanghänel, Thomas (Author)
Format: Article (Journal)
Language:English
Published: 2011
In: Radiochimica acta
Year: 2011, Volume: 99, Issue: 1, Pages: 13-16
ISSN:2193-3405
DOI:10.1524/ract.2011.1794
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1524/ract.2011.1794
Verlag, lizenzpflichtig, Volltext: https://www.degruyterbrill.com/document/doi/10.1524/ract.2011.1794/html
Get full text
Author Notes:S. Trumm, G. Wipff, Andreas Geist, Petra J. Panak, and Thomas Fanghänel

MARC

LEADER 00000caa a2200000 c 4500
001 1822741211
003 DE-627
005 20250530004535.0
007 cr uuu---uuuuu
008 221117s2011 xx |||||o 00| ||eng c
024 7 |a 10.1524/ract.2011.1794  |2 doi 
035 |a (DE-627)1822741211 
035 |a (DE-599)KXP1822741211 
035 |a (OCoLC)1389751182 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Trumm, Sascha  |e VerfasserIn  |0 (DE-588)140989935  |0 (DE-627)623812614  |0 (DE-576)32168530X  |4 aut 
245 1 0 |a Optimising BTP ligands by tuning their basicity  |c S. Trumm, G. Wipff, Andreas Geist, Petra J. Panak, and Thomas Fanghänel 
264 1 |c 2011 
300 |a 4 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Erstmals am 16. Dezember 2010 online veröffentlicht 
500 |a Gesehen am 17.11.2022 
520 |a A novel approach for the optimisation of extractants for the actinide(III)/lanthanide(III) separation is presented. Two BTP ligands are synthesised carrying OMe or Cl moieties on the pyridine ring, thus altering the electronic structure of the aromatic system. The influence of functionalisation on the ligand basicity is determined both spectroscopically and by quantum chemical calculations. Furthermore, we show that both distribution ratios and separation factors for Am(III)/Eu(III) separation increase upon increase of ligand basicity. 
650 4 |a Americium(III) 
650 4 |a Europium(III) 
650 4 |a SANEX process 
650 4 |a Separation 
650 4 |a Substituted BTP 
700 1 |a Wipff, G.  |e VerfasserIn  |4 aut 
700 1 |a Geist, Andreas  |e VerfasserIn  |4 aut 
700 1 |a Panak, Petra  |e VerfasserIn  |0 (DE-588)1084656000  |0 (DE-627)848640217  |0 (DE-576)456626727  |4 aut 
700 1 |a Fanghänel, Thomas  |d 1955-  |e VerfasserIn  |0 (DE-588)1152890522  |0 (DE-627)1014291208  |0 (DE-576)499947347  |4 aut 
773 0 8 |i Enthalten in  |t Radiochimica acta  |d Berlin : De Gruyter, 1962  |g 99(2011), 1, Seite 13-16  |h Online-Ressource  |w (DE-627)325787964  |w (DE-600)2039575-9  |w (DE-576)282498265  |x 2193-3405  |7 nnas  |a Optimising BTP ligands by tuning their basicity 
773 1 8 |g volume:99  |g year:2011  |g number:1  |g pages:13-16  |g extent:4  |a Optimising BTP ligands by tuning their basicity 
856 4 0 |u https://doi.org/10.1524/ract.2011.1794  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://www.degruyterbrill.com/document/doi/10.1524/ract.2011.1794/html  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20221117 
993 |a Article 
994 |a 2011 
998 |g 1152890522  |a Fanghänel, Thomas  |m 1152890522:Fanghänel, Thomas  |d 120000  |d 120300  |e 120000PF1152890522  |e 120300PF1152890522  |k 0/120000/  |k 1/120000/120300/  |p 5  |y j 
998 |g 1084656000  |a Panak, Petra  |m 1084656000:Panak, Petra  |d 120000  |d 120300  |e 120000PP1084656000  |e 120300PP1084656000  |k 0/120000/  |k 1/120000/120300/  |p 4 
998 |g 140989935  |a Trumm, Sascha  |m 140989935:Trumm, Sascha  |p 1  |x j 
999 |a KXP-PPN1822741211  |e 4213230945 
BIB |a Y 
SER |a journal 
JSO |a {"person":[{"roleDisplay":"VerfasserIn","family":"Trumm","given":"Sascha","role":"aut","display":"Trumm, Sascha"},{"role":"aut","display":"Wipff, G.","roleDisplay":"VerfasserIn","family":"Wipff","given":"G."},{"roleDisplay":"VerfasserIn","given":"Andreas","family":"Geist","role":"aut","display":"Geist, Andreas"},{"display":"Panak, Petra","role":"aut","family":"Panak","given":"Petra","roleDisplay":"VerfasserIn"},{"display":"Fanghänel, Thomas","role":"aut","family":"Fanghänel","given":"Thomas","roleDisplay":"VerfasserIn"}],"physDesc":[{"extent":"4 S."}],"origin":[{"dateIssuedKey":"2011","dateIssuedDisp":"2011"}],"language":["eng"],"relHost":[{"physDesc":[{"extent":"Online-Ressource"}],"pubHistory":["1.1962/63 -"],"title":[{"title":"Radiochimica acta","title_sort":"Radiochimica acta","subtitle":"international journal for chemical aspects of nuclear science and technology"}],"disp":"Optimising BTP ligands by tuning their basicityRadiochimica acta","language":["eng"],"origin":[{"publisherPlace":"Berlin ; München","publisher":"De Gruyter ; Oldenbourg","dateIssuedDisp":"1962-","dateIssuedKey":"1962"}],"recId":"325787964","type":{"media":"Online-Ressource","bibl":"periodical"},"id":{"zdb":["2039575-9"],"issn":["2193-3405"],"eki":["325787964"]},"part":{"issue":"1","extent":"4","volume":"99","year":"2011","text":"99(2011), 1, Seite 13-16","pages":"13-16"},"titleAlt":[{"title":"Radiochimica acta online"}],"note":["Gesehen am 02.04.15"]}],"recId":"1822741211","title":[{"title":"Optimising BTP ligands by tuning their basicity","title_sort":"Optimising BTP ligands by tuning their basicity"}],"id":{"doi":["10.1524/ract.2011.1794"],"eki":["1822741211"]},"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Erstmals am 16. Dezember 2010 online veröffentlicht","Gesehen am 17.11.2022"],"name":{"displayForm":["S. Trumm, G. Wipff, Andreas Geist, Petra J. Panak, and Thomas Fanghänel"]}} 
SRT |a TRUMMSASCHOPTIMISING2011 

Similar Items