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Quinolyl-functionalised Cp-chromium polymerisation catalysts: synthesis and crystal structures of alkylation products

The quinolyl-functionalised Cp-chromium(III) complexes 1 and 2, which serve as precursors for highly active olefin polymerisation catalysts, were alkylated with benzylmagnesium chloride. From these reactions, the new metal complexes 4, 5 and 6 were obtained and structurally characterised. The expect...

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Hauptverfasser: Enders, Markus (VerfasserIn) , Fernández, Pablo (VerfasserIn) , Mihan, Shahram (VerfasserIn) , Pritzkow, Hans (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2003
In: Journal of organometallic chemistry
Year: 2003, Jahrgang: 687, Heft: 1, Pages: 125-130
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2003.07.017
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2003.07.017
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0022328X03008507
Volltext
Verfasserangaben:Markus Enders, Pablo Fernández, Shahram Mihan, Hans Pritzkow

MARC

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520 |a The quinolyl-functionalised Cp-chromium(III) complexes 1 and 2, which serve as precursors for highly active olefin polymerisation catalysts, were alkylated with benzylmagnesium chloride. From these reactions, the new metal complexes 4, 5 and 6 were obtained and structurally characterised. The expected alkylchromium compound 4 is formed together with complex 5, where the nucleophile replaced a hydrogen atom at the quinoline substituent. The dinuclear complex 6 is formed by nucleophile addition, rearrangement and dimerisation. 
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