Rhodium-carbonyl complexes with a quinolyl functionalized Cp-ligand: synthesis and photochemical activation

Dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) (1) was prepared by the reaction of [Rh(CO)2Cl]2 with 2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl-potassium. Irradiation of 1 in chloroform or dichloromethane as solvent leads to the formation of dichloro[η5-2,3,4,5-t...

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Hauptverfasser: Enders, Markus (VerfasserIn) , Kohl, Gerald (VerfasserIn) , Pritzkow, Hans (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2004
In: Journal of organometallic chemistry
Year: 2004, Jahrgang: 689, Heft: 19, Pages: 3024-3030
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2004.06.046
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2004.06.046
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0022328X04004589
Volltext
Verfasserangaben:Markus Enders, Gerald Kohl, Hans Pritzkow

MARC

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520 |a Dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) (1) was prepared by the reaction of [Rh(CO)2Cl]2 with 2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl-potassium. Irradiation of 1 in chloroform or dichloromethane as solvent leads to the formation of dichloro[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(III) (2). When Rh6(CO)16 is present, the cluster adds to the 8-quinolyl-cp-rhodium fragment and the compound [η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium-di-μ-carbonyl-hexarhodiumtetradecacarbonyl (3) is formed in 65% yield. The coordination sphere of the rhodium(III) atom in compound 2 and of the rhodium(I) atom in 3 is completed by a coordination of the quinolyl moiety. This was revealed by NMR spectroscopy as well as by X-ray analyses. 
650 4 |a -Functionalized cyclopentadienyl ligands 
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