An evaluation of ligand properties of neutral and anionic tris(imidazol-2-yl)phosphines
In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In additi...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2004
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2004, Jahrgang: 630, Heft: 10, Pages: 1501-1506 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200400149 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200400149 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200400149 |
| Verfasserangaben: | Markus Enders, Olaf Fritz, Hans Pritzkow |
MARC
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| 520 | |a In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In addition, an anionic ligand precursor was characterized by X-Ray analysis and its reactivity towards transition metal halides assayed. | ||
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| 650 | 4 | |a Tris(imidazolyl)phosphines | |
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