Paramagnetic (1,3-diborolyl)ruthenium triple-decker complexes and transformation into diamagnetic complexes having bridging 1,3-diborafulvene ligands
The paramagnetic triple-decker complexes [(Cp*Ru)2μ-(CMe)3(BCl)(BMe)] (3b) and [(Cp*Ru)2μ-(CMe)3(BCl)2] (3c) are formed by refluxing a mixture of [Cp*RuCl]4 and pentamethyl-2,3-dihydro-1,3-diborole in thf. In CH2Cl2 under air complex 3b slowly looses a hydrogen atom with formation of the diamagnetic...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2010
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| In: |
European journal of inorganic chemistry
Year: 2010, Heft: 19, Pages: 2911-2918 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.200901232 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.200901232 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200901232 
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| Verfasserangaben: | Elena V. Mutseneck, Hubert Wadepohl, Markus Enders, Alexander R. Kudinov, and Walter Siebert |
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| 245 | 1 | 0 | |a Paramagnetic (1,3-diborolyl)ruthenium triple-decker complexes and transformation into diamagnetic complexes having bridging 1,3-diborafulvene ligands |c Elena V. Mutseneck, Hubert Wadepohl, Markus Enders, Alexander R. Kudinov, and Walter Siebert |
| 246 | 3 | 3 | |a Paramagnetic (one, three -diborolyl)ruthenium triple-decker complexes and transformation into diamagnetic complexes having bridging 1,3-diborafulvene ligands |
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| 520 | |a The paramagnetic triple-decker complexes [(Cp*Ru)2μ-(CMe)3(BCl)(BMe)] (3b) and [(Cp*Ru)2μ-(CMe)3(BCl)2] (3c) are formed by refluxing a mixture of [Cp*RuCl]4 and pentamethyl-2,3-dihydro-1,3-diborole in thf. In CH2Cl2 under air complex 3b slowly looses a hydrogen atom with formation of the diamagnetic triple-decker [(Cp*Ru)2μ-η5:η6-(CMe)3(BCl)(BCH2)] (4b) with the unsymmetrical dihydrodiborafulvene derivative in a bridging position. The analogous complex [(Cp*Ru)2μ-η5:η6-(CMe)3(BMe)-(BCH2)] (4a) is obtained by interaction of HCl with the triple-decker [(Cp*Ru)2μ-(CMe)3(BMe)2] (3a). According to calculations, complexes 4a and 4b have an almost non-distorted triple-decker arrangement with a strong bending of the B=CH2 group toward one of the Ru atoms. For the formation of 3b and 3c the chloro-containing sandwich complexes [Cp*Ruη5-(CMe)3(BCl)(BR1)] (2b,c; R1 = Me, Cl) are proposed as intermediates. The constitutions of the complexes are derived from NMR, MS and DFT data, and the molecular structure of 3b is confirmed by an X-ray diffraction analysis. | ||
| 650 | 4 | |a Dihydrodiborafulvene | |
| 650 | 4 | |a Paramagnetic triple-decker | |
| 650 | 4 | |a Ruthenium | |
| 650 | 4 | |a Sandwich compounds | |
| 650 | 4 | |a Slipped triple-decker | |
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