Synthesis of a stable B2H5+ analogue by protonation of a double base-stabilized diborane(4)
Polarity of H+ reversed: The synthesis of [B2H3(hpp)2]+I−,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted i...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2009
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| In: |
Angewandte Chemie. International edition
Year: 2009, Jahrgang: 48, Heft: 30, Pages: 5538-5541 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200901842 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200901842 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200901842 
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| Verfasserangaben: | Oxana Ciobanu, Elisabeth Kaifer, Markus Enders, and Hans-Jörg Himmel |
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| 246 | 3 | 3 | |a Synthesis of a stable B 2 H 5 + analogue by protonation of a double base-stabilized diborane(4) |
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| 500 | |a First published: 08 July 2009 | ||
| 500 | |a Gesehen am 29.11.2022 | ||
| 520 | |a Polarity of H+ reversed: The synthesis of [B2H3(hpp)2]+I−,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted into a hydride. | ||
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| 650 | 4 | |a protonation | |
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