Synthesis, structure, and rearrangement of 1,3-Dibora(5)radialenes
The new 1,3-bis(dimethylamino) derivative 1 is isoelectronic with decamethyl[5]radialene. The analogous 1,3-dimethyl compound 2 undergoes slow 1,5-sigmatropic H shift to give a 1,3-diborafulvene. This process is faster in the reaction with [Mo(CO)6], whereby the product is the [Mo(CO)4] complex 3.
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
1991
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| In: |
Angewandte Chemie. International edition
Year: 1991, Jahrgang: 30, Heft: 1, Pages: 84-85 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.199100841 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.199100841 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.199100841 
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| Verfasserangaben: | Markus Enders, Albrecht Krämer, Hans Pritzkow, and Walter Siebert |
| Zusammenfassung: | The new 1,3-bis(dimethylamino) derivative 1 is isoelectronic with decamethyl[5]radialene. The analogous 1,3-dimethyl compound 2 undergoes slow 1,5-sigmatropic H shift to give a 1,3-diborafulvene. This process is faster in the reaction with [Mo(CO)6], whereby the product is the [Mo(CO)4] complex 3. |
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| Beschreibung: | Gesehen am 30.11.2022 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.199100841 |