Formation of a 2,5-diborabicyclo(2.1.1)hexane derivative and its conversion to a tetracarbahexaborane: dedicated to Professor Worfsang Beck on the occasion of his 60th birthday
A framework rearrangement and a migration of a hydrogen atom result in the formation of the carborane 2 from the bridged boretane 1. The crystal structure analysis shows that the four-membered ring in 1 is extremely folded. This suggests a 1,3-transannular interaction between the free p orbital at t...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
May 1992
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| In: |
Angewandte Chemie. International edition
Year: 1992, Jahrgang: 31, Heft: 5, Pages: 606-607 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.199206061 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.199206061 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.199206061 
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| Verfasserangaben: | Markus Enders, Hans Pritzkow, and Walter Siebert |
| Zusammenfassung: | A framework rearrangement and a migration of a hydrogen atom result in the formation of the carborane 2 from the bridged boretane 1. The crystal structure analysis shows that the four-membered ring in 1 is extremely folded. This suggests a 1,3-transannular interaction between the free p orbital at the B atom and the exocyclic double bond at the C atom. Both the formation of 1 from the nonisolable (tBuBCHCCMe2)2 dimer and the rearrangement to 2 are novel reactions. |
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| Beschreibung: | Gefördert durch: Deutsche Forschungsgemeinschaft (SFB 247), Fonds der Chemischen Industrie, und der BASF AG Gesehen am 30.11.2022 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.199206061 |