Synthesis, structure, and unprecedented solubility of lipophilic borate salts
The multi-gram scale preparation of halide free lipophilic borate salts from inexpensive precursor compounds 3,3′,5,5′-tetra-tert-butyl-2,2′-biphenol and tetrahydridoboranate salts is reported. The so-called “bortebate” anion is more stable against water and bases than its aluminum analog “altebate”...
Gespeichert in:
| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2011
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| In: |
Inorganica chimica acta
Year: 2011, Jahrgang: 369, Heft: 1, Pages: 71-75 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2010.12.039 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.ica.2010.12.039 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0020169310008819 
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| Verfasserangaben: | Michael Wrede, Viktoria Ganza, Geraldt Kannenberg, Frank Rominger, Bernd F. Straub |
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| 520 | |a The multi-gram scale preparation of halide free lipophilic borate salts from inexpensive precursor compounds 3,3′,5,5′-tetra-tert-butyl-2,2′-biphenol and tetrahydridoboranate salts is reported. The so-called “bortebate” anion is more stable against water and bases than its aluminum analog “altebate”, but bortebate formation is significantly slower. Bortebate salts are highly soluble in hydrocarbon solvents, e.g. >35mmol/L lithium bortebate in pentane at 20°C. Quantitative salt metathesis reactions between sodium bortebate and halide salts can be easily achieved by precipitation of the sodium halide in methylene chloride. | ||
| 650 | 4 | |a Anions | |
| 650 | 4 | |a Boron | |
| 650 | 4 | |a Lipophilicity | |
| 650 | 4 | |a Sodium | |
| 650 | 4 | |a Solubility | |
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