An oxocobalt(IV) complex stabilized by Lewis acid interactions with scandium(III) ions
An elusive S=3/2 oxocobalt(IV) complex is stabilized by a Lewis acid interaction with a scandium(III) ion. The CoIV-O-Sc3+ unit, characterized by spectroscopic and DFT methods, is a stronger electron-transfer and H-atom abstraction agent but weaker oxo-transfer agent than the corresponding FeIVO co...
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| Hauptverfasser: | , , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Jahrgang: 50, Heft: 7, Pages: 1711-1715 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201005869 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201005869 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201005869 
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| Verfasserangaben: | Florian Felix Pfaff, Subrata Kundu, Marcel Risch, Shanthi Pandian, Florian Heims, Iweta Pryjomska-Ray, Peter Haack, Ramona Metzinger, Eckhard Bill, Holger Dau, Peter Comba, and Kallol Ray |
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| 245 | 1 | 3 | |a An oxocobalt(IV) complex stabilized by Lewis acid interactions with scandium(III) ions |c Florian Felix Pfaff, Subrata Kundu, Marcel Risch, Shanthi Pandian, Florian Heims, Iweta Pryjomska-Ray, Peter Haack, Ramona Metzinger, Eckhard Bill, Holger Dau, Peter Comba, and Kallol Ray |
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| 520 | |a An elusive S=3/2 oxocobalt(IV) complex is stabilized by a Lewis acid interaction with a scandium(III) ion. The CoIV-O-Sc3+ unit, characterized by spectroscopic and DFT methods, is a stronger electron-transfer and H-atom abstraction agent but weaker oxo-transfer agent than the corresponding FeIVO complex (see scheme; L=tris[2-(N-tetramethylguanidyl)ethyl]amine). | ||
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| 650 | 4 | |a terminal coordination | |
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