Metal silylenes generated by double silicon-hydrogen activation: key intermediates in the rhodium-catalyzed hydrosilylation of ketones : dedicated to Professor Helmut Werner on the occasion of his 75th birthday
Wenig Aktivierungsenergie benötigt die Hydrosilylierung von Ketonen mit R2SiH2, an der Rhodiumsilylene beteiligt sind, die durch doppelte Si-H-Aktivierung am Metall entstehen. Eine DFT-Studie der Reaktionsmechanismen passt zu den experimentellen Befunden, vor allem zur höheren Reaktionsgeschwindig...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
2009
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| In: |
Angewandte Chemie
Year: 2009, Jahrgang: 121, Heft: 9, Pages: 1637-1641 |
| ISSN: | 1521-3757 |
| DOI: | 10.1002/ange.200804993 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.200804993 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.200804993 
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| Verfasserangaben: | Nathanaëlle Schneider, Markus Finger, Christian Haferkemper, Stéphane Bellemin-Laponnaz, Peter Hofmann, and Lutz H. Gade |
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