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Metal silylenes generated by double silicon-hydrogen activation: key intermediates in the rhodium-catalyzed hydrosilylation of ketones : dedicated to Professor Helmut Werner on the occasion of his 75th birthday

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Wenig Aktivierungsenergie benötigt die Hydrosilylierung von Ketonen mit R2SiH2, an der Rhodiumsilylene beteiligt sind, die durch doppelte Si-H-Aktivierung am Metall entstehen. Eine DFT-Studie der Reaktionsmechanismen passt zu den experimentellen Befunden, vor allem zur höheren Reaktionsgeschwindig...

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Main Authors: Schneider, Nathanaëlle (Author) , Finger, Markus (Author) , Haferkemper, Christian (Author) , Bellemin-Laponnaz, Stéphane (Author) , Hofmann, Peter (Author) , Gade, Lutz H. (Author)
Format: Article (Journal) Festschrift
Language:English
Published: 2009
In: Angewandte Chemie
Year: 2009, Volume: 121, Issue: 9, Pages: 1637-1641
ISSN:1521-3757
DOI:10.1002/ange.200804993
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Festschrift
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.200804993
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.200804993
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Author Notes:Nathanaëlle Schneider, Markus Finger, Christian Haferkemper, Stéphane Bellemin-Laponnaz, Peter Hofmann, and Lutz H. Gade
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Metal silylenes generated by double silicon-hydrogen activation: key intermediates in the rhodium-catalyzed hydrosilylation of ketones : dedicated to Professor Helmut Werner on the... by Schneider, Nathanaëlle (Author) , Finger, Markus (Author) , Haferkemper, Christian (Author) , Bellemin-Laponnaz, Stéphane (Author) , Hofmann, Peter (Author) , Gade, Lutz H. (Author) ,


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