The role of the “ligand periphery” in the coordination of tripodal triamidostannates(II) to iridium: simple ligation vs. cyclometallation : dedicated to Professor Heinrich Nöth on the occasion of his 80th birthday
Reaction of the triamidostannates(II) MeSiSiMe2N(3,5-xyl)3SnLi(OEt2) (2a) and MeSiSiMe2N(p-tol)3SnLi(OEt2) (2b) with [IrCl(CO)(PPh3)2] gave the IrI-Sn complex [MeSiSiMe2N(3,5-xyl)3SnIr(PPh3)2(CO)] (3a) for the former. In contrast, for the tolyl stannate CH-activation occurred to give the IrIII compo...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
2008
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2008, Jahrgang: 634, Heft: 8, Pages: 1378-1382 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200800090 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200800090 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200800090 
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| Verfasserangaben: | Michaela Kilian, Hubert Wadepohl, and Lutz H. Gade |
MARC
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| 245 | 1 | 4 | |a The role of the “ligand periphery” in the coordination of tripodal triamidostannates(II) to iridium |b simple ligation vs. cyclometallation : dedicated to Professor Heinrich Nöth on the occasion of his 80th birthday |c Michaela Kilian, Hubert Wadepohl, and Lutz H. Gade |
| 246 | 3 | 3 | |a The role of the “ligand periphery” in the coordination of tripodal triamidostannates(two) to iridium |
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| 520 | |a Reaction of the triamidostannates(II) MeSiSiMe2N(3,5-xyl)3SnLi(OEt2) (2a) and MeSiSiMe2N(p-tol)3SnLi(OEt2) (2b) with [IrCl(CO)(PPh3)2] gave the IrI-Sn complex [MeSiSiMe2N(3,5-xyl)3SnIr(PPh3)2(CO)] (3a) for the former. In contrast, for the tolyl stannate CH-activation occurred to give the IrIII compound [MeSiSiMe2N(p-tol)2SiMe2N(2-C6H3-4-CH3)SnIr(H)(PPh3)2(CO)] (3b). The latter is thus avoided by introduction of suitably placed substituents in the peripheral aryl groups of the triamidostannate ligand. | ||
| 650 | 4 | |a Crystal structure | |
| 650 | 4 | |a Heterodimetallic complexes | |
| 650 | 4 | |a Iridium | |
| 650 | 4 | |a Triamidostannates | |
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