A stable hexaazaoctacene cruciform σ-dimer: dedicated to Professor Klaus Müllen on the occasion of his 75th birthday
Buchwald-Hartwig coupling of a triisopropylsilyl (TIPS)-ethynylated dibromo-N,N'-dihydrotetraazapentacene with 1,4-bis(TIPS-ethynyl)-2,3-diaminonaphthalene furnishes a dihydrohexaazaoctacene. Its oxidation with MnO2 results in a 7,7'-bi(hexaazaoctacenyl). In addition to eight TIPS-ethynyl...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
September 23, 2022
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| In: |
Advanced science
Year: 2022, Jahrgang: 9, Heft: 27, Pages: 1-6 |
| ISSN: | 2198-3844 |
| DOI: | 10.1002/advs.202202710 |
| Schlagworte: | |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/advs.202202710 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/advs.202202710 |
| Verfasserangaben: | Steffen Maier, Fabian Jester, Marvin T. Hoffmann, Frank Rominger, Jan Freudenberg, Andreas Dreuw, and Uwe H.F. Bunz |
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| 520 | |a Buchwald-Hartwig coupling of a triisopropylsilyl (TIPS)-ethynylated dibromo-N,N'-dihydrotetraazapentacene with 1,4-bis(TIPS-ethynyl)-2,3-diaminonaphthalene furnishes a dihydrohexaazaoctacene. Its oxidation with MnO2 results in a 7,7'-bi(hexaazaoctacenyl). In addition to eight TIPS-ethynyl groups, the bioctacene motif protects the azaoctacene subunits. The biazaoctacenyl displays a τ1/2 of > 5 d in dilute solution under ambient conditions. In the crystalline state it is persistent for > 10 months. | ||
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