Allylic peroxidations with bis(2-pyridylimino)isoindolato-cobalt and -iron complexes: dedicated to Professor Michael Veith on the occasion of his 60th birthday
Several novel substituted bis(2-pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 - 6, Fe: 7) have been synthesized by reaction of bis(2-pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1-6 with 1.5 - 2 molar equiv...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
2004
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2004, Jahrgang: 630, Heft: 12, Pages: 1962-1968 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200400253 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200400253 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200400253 
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| Verfasserangaben: | Markus B. Meder, Bettina A. Siggelkow, and Lutz H. Gade |
MARC
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| 245 | 1 | 0 | |a Allylic peroxidations with bis(2-pyridylimino)isoindolato-cobalt and -iron complexes |b dedicated to Professor Michael Veith on the occasion of his 60th birthday |c Markus B. Meder, Bettina A. Siggelkow, and Lutz H. Gade |
| 246 | 3 | 3 | |a Allylic peroxidations with bis(two -pyridylimino)isoindolato-cobalt and -iron complexes |
| 264 | 1 | |c 2004 | |
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| 500 | |a First published: 21 October 2004 | ||
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| 520 | |a Several novel substituted bis(2-pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 - 6, Fe: 7) have been synthesized by reaction of bis(2-pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1-6 with 1.5 - 2 molar equivalents of t-BuOOH gave the corresponding alkylperoxocobalt(III) complexes [Co(BPI)(OAc)(OOtBu)] (10 - 15). Using an aqueous solution of t-BuOOH (70 %), cyclohexene was selectively catalytically oxidized to the dialkylperoxide cyclohex-2-ene-1-t-butylperoxide. | ||
| 650 | 4 | |a Allylic peroxidation | |
| 650 | 4 | |a Cobalt | |
| 650 | 4 | |a Iron | |
| 650 | 4 | |a N-donor ligands | |
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| 700 | 1 | |a Veith, Michael |d 1944- |e GefeierteR |0 (DE-588)142822213 |0 (DE-627)640138527 |0 (DE-576)33357429X |4 hnr | |
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