Self-assembly of a cyclic Zn4O4 tetramer by aerobic oxidation of a bisoxazoline: a molecular "Nest" for nucleophilic OH-

Nesting hydroxide: Coordination and aerobic oxidation of a bisoxazoline Me2box is coupled with self-assembly to form a highly ordered [(Me2box)O4Zn4]4+ complex. The metallamacrocycle acts as a nest-like hydroxide receptor (see scheme, right) and shows catalytic phosphatase activity.

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Bibliographische Detailangaben
Hauptverfasser: Jacques, Béatrice (VerfasserIn) , Dro, Clémence (VerfasserIn) , Bellemin-Laponnaz, Stéphane (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Gade, Lutz H. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 27 May 2008
In: Angewandte Chemie. International edition
Year: 2008, Jahrgang: 47, Heft: 24, Pages: 4546-4550
ISSN:1521-3773
DOI:10.1002/anie.200800870
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200800870
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200800870
Volltext
Verfasserangaben:Béatrice Jacques, Clémence Dro, Stéphane Bellemin-Laponnaz, Hubert Wadepohl, and Lutz H. Gade

MARC

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