Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species
Pincer-stabilized nickel(I) complexes readily react with molecular oxygen to form dinuclear 1,2-μ-peroxo-bridged nickel(II) complexes, which are the major components of a dynamic equilibrium with the corresponding mononuclear superoxo species. The peroxo complexes further react with hydrogen peroxid...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
20 February 2015
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| In: |
Angewandte Chemie
Year: 2015, Jahrgang: 127, Heft: 16, Pages: 4962-4966 |
| ISSN: | 1521-3757 |
| DOI: | 10.1002/ange.201500141 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.201500141 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201500141 
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| Verfasserangaben: | Christoph A. Rettenmeier, Hubert Wadepohl, and Lutz H. Gade |
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| 245 | 1 | 0 | |a Structural characterization of a hydroperoxo nickel complex and its autoxidation |b mechanism of interconversion between peroxo, superoxo, and hydroperoxo species |c Christoph A. Rettenmeier, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Pincer-stabilized nickel(I) complexes readily react with molecular oxygen to form dinuclear 1,2-μ-peroxo-bridged nickel(II) complexes, which are the major components of a dynamic equilibrium with the corresponding mononuclear superoxo species. The peroxo complexes further react with hydrogen peroxide to give the corresponding nickel(II) hydroperoxides. One of these hitherto elusive species was characterized by X-ray diffraction for the first time [O-O bond length: 1.492(2) Å]. | ||
| 650 | 4 | |a Autoxidation | |
| 650 | 4 | |a Hydroperoxide | |
| 650 | 4 | |a Nickel | |
| 650 | 4 | |a Peroxide | |
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