Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species
Pincer-stabilized nickel(I) complexes readily react with molecular oxygen to form dinuclear 1,2-μ-peroxo-bridged nickel(II) complexes, which are the major components of a dynamic equilibrium with the corresponding mononuclear superoxo species. The peroxo complexes further react with hydrogen peroxid...
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| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
20 February 2015
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| In: |
Angewandte Chemie
Year: 2015, Volume: 127, Issue: 16, Pages: 4962-4966 |
| ISSN: | 1521-3757 |
| DOI: | 10.1002/ange.201500141 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.201500141 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201500141 
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| Author Notes: | Christoph A. Rettenmeier, Hubert Wadepohl, and Lutz H. Gade |
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