Radical changes in Lewis acid catalysis: matching metal and substrate
Whereas the stereochemical rigidity of the coordination sphere of boxmi/CuII catalysts is key to achieving high enantioselectivity in the electrophilic alkylation of β-ketoesters, this pathway is outperformed by a radical process for the corresponding catalytic transformation of oxindoles, giving ri...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
02 June 2016
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| In: |
Angewandte Chemie
Year: 2016, Jahrgang: 128, Heft: 27, Pages: 7983-7987 |
| ISSN: | 1521-3757 |
| DOI: | 10.1002/ange.201603072 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.201603072 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201603072 
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| Verfasserangaben: | Tim Bleith, Qing-Hai Deng, Hubert Wadepohl, and Lutz H. Gade |
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