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Mechanism-based enantiodivergence in manganese reduction catalysis: a chiral pincer complex for the highly enantioselective hydroboration of ketones

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A manganese alkyl complex containing a chiral bis(oxazolinyl-methylidene)isoindoline pincer ligand is a precatalyst for a catalytic system of unprecedented activity and selectivity in the enantioselective hydroboration of ketones, thus producing preparatively useful chiral alcohols in excellent yiel...

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Main Authors: Vasilenko, Vladislav (Author) , Blasius, Clemens K. (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 24 May 2017
In: Angewandte Chemie
Year: 2017, Volume: 129, Issue: 29, Pages: 8513-8517
ISSN:1521-3757
DOI:10.1002/ange.201704184
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ange.201704184
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201704184
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Author Notes:Vladislav Vasilenko, Clemens K. Blasius, Hubert Wadepohl, and Lutz H. Gade
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Mechanism-based enantiodivergence in manganese reduction catalysis: a chiral pincer complex for the highly enantioselective hydroboration of ketones by Vasilenko, Vladislav (Author) , Blasius, Clemens K. (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author) ,


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