Transforming surface coordination polymers into covalent surface polymers: linked polycondensed aromatics through oligomerization of N-heterocyclic carbene intermediates
Isomerize and polymerize! Thermally induced tautomerization of the N-heteropolycyclic 1,3,8,10-tetraazaperopyrene to a Wanzlick-type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective struc...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
10 March 2008
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| In: |
Angewandte Chemie. International edition
Year: 2008, Jahrgang: 47, Heft: 13, Pages: 2414-2417 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200704072 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200704072 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200704072 
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| Verfasserangaben: | Manfred Matena, Till Riehm, Meike Stöhr, Thomas A. Jung, and Lutz H. Gade |
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| 520 | |a Isomerize and polymerize! Thermally induced tautomerization of the N-heteropolycyclic 1,3,8,10-tetraazaperopyrene to a Wanzlick-type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective structures superimposed on the STM images. | ||
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