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Transforming surface coordination polymers into covalent surface polymers: linked polycondensed aromatics through oligomerization of N-heterocyclic carbene intermediates

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Isomerize and polymerize! Thermally induced tautomerization of the N-heteropolycyclic 1,3,8,10-tetraazaperopyrene to a Wanzlick-type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective struc...

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Main Authors: Matena, Manfred (Author) , Riehm, Till (Author) , Stöhr, Meike (Author) , Jung, Thomas A. (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 10 March 2008
In: Angewandte Chemie. International edition
Year: 2008, Volume: 47, Issue: 13, Pages: 2414-2417
ISSN:1521-3773
DOI:10.1002/anie.200704072
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200704072
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200704072
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Author Notes:Manfred Matena, Till Riehm, Meike Stöhr, Thomas A. Jung, and Lutz H. Gade
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Transforming surface coordination polymers into covalent surface polymers: linked polycondensed aromatics through oligomerization of N-heterocyclic carbene intermediates by Matena, Manfred (Author) , Riehm, Till (Author) , Stöhr, Meike (Author) , Jung, Thomas A. (Author) , Gade, Lutz H. (Author) ,


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