Assembly of an R3N52- chain by cycloaddition of a hydrazinediide and an azide at zirconium and its thermal fragmentation
Breaking the chain: Reaction of a zirconium hydrazinediide with organoazides gives 2-pentazene-1,4-diyl complexes, such as [Zr(N2TBSNpy)N(Ad)N3NPh2] (C gray, N blue, Si green, Zr turquoise), by formal [2+3] cycloaddition. Bonding within the N5 chain is investigated using density functional calculati...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
03 March 2009
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| In: |
Angewandte Chemie. International edition
Year: 2009, Volume: 48, Issue: 12, Pages: 2152-2156 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200805631 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200805631 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200805631 
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| Author Notes: | Thorsten Gehrmann, Julio Lloret Fillol, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Breaking the chain: Reaction of a zirconium hydrazinediide with organoazides gives 2-pentazene-1,4-diyl complexes, such as [Zr(N2TBSNpy)N(Ad)N3NPh2] (C gray, N blue, Si green, Zr turquoise), by formal [2+3] cycloaddition. Bonding within the N5 chain is investigated using density functional calculations. These complexes thermally eject N2 to give side-on bonded diazenides. | ||
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