A zirconium hydrazide as a synthon for a metallanitrene equivalent: atom-by-atom assembly of (EN2)2- units (E=S, Se) by chalcogen-atom transfer in the coordination sphere of a transition metal
Piece by piece: Hydrazides at zirconium centers undergo facile NN bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom-by-atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS=tBuMe2Si).
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
02 November 2007
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| In: |
Angewandte Chemie. International edition
Year: 2007, Volume: 46, Issue: 44, Pages: 8426-8430 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200703938 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200703938 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200703938 
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| Author Notes: | Heike Herrmann, Julio Lloret Fillol, Hubert Wadepohl, and Lutz H. Gade |
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