Crystal chemistry of the system Bi2O3-CdO-GeO2

The ternary phase diagram of the system Bi2O3-CdO-GeO2 was investigated in several isothermal sections using predominantly X-ray powder diffraction. The following phases are described with respect to their crystal chemistry, phase relations and powder patterns: Bi2−2xCd2x(O3−x⍽9+x) (solid solution w...

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Bibliographic Details
Main Authors: Wies, Stefan (Author) , Eysel, Walter (Author)
Format: Article (Journal)
Language:English
Published: 1996
In: Powder diffraction
Year: 1996, Volume: 11, Issue: 2, Pages: 80-84
ISSN:1945-7413
DOI:10.1017/S0885715600009015
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1017/S0885715600009015
Verlag, lizenzpflichtig, Volltext: https://www.cambridge.org/core/journals/powder-diffraction/article/abs/crystal-chemistry-of-the-system-bi2o3cdogeo2ab/DC0EDBD43D5B4C7B2DDD96B38FB8FA62#
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Author Notes:S. Wies, W. Eysel

MARC

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520 |a The ternary phase diagram of the system Bi2O3-CdO-GeO2 was investigated in several isothermal sections using predominantly X-ray powder diffraction. The following phases are described with respect to their crystal chemistry, phase relations and powder patterns: Bi2−2xCd2x(O3−x⍽9+x) (solid solution with anti-α-AgI structure), CdGeO3 (complicated polymorphism), Bi12GeO20 (stoichiometric sillenite), Cd-sillenite (solid solution), Bi1.8Cd0.2GeO4.9 (metastable, new phase, new structure type with GeO5 polyhedra), Bi2CdGeO6 (new ternary oxide, new structure type). 
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