Immobilized Sonogashira catalyst systems: new insights by multinuclear HRMAS NMR studies
A new chelate phosphine linker and its Pd and Cu complexes have been synthesized and immobilized. The solvent impact on these immobilized species, their mobility, and coordination preferences have been studied in situ by HRMAS (High-Resolution Magic Angle Spinning) NMR. The catalyst recycling charac...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
4 January 2011
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| In: |
Chemical communications
Year: 2011, Jahrgang: 47, Heft: 7, Pages: 2059-2061 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C0CC04194G |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C0CC04194G Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2011/cc/c0cc04194g |
| Verfasserangaben: | Tobias Posset, Johannes Guenther, Jacqueline Pope, Thomas Oeser and Janet Blümel |
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| 520 | |a A new chelate phosphine linker and its Pd and Cu complexes have been synthesized and immobilized. The solvent impact on these immobilized species, their mobility, and coordination preferences have been studied in situ by HRMAS (High-Resolution Magic Angle Spinning) NMR. The catalyst recycling characteristics match the HRMAS results. | ||
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