Regioselective hydrothiolation of allenoates through a Ca(OTf)2-promoted three-component reaction
An approach to synthesize α-substituted alkene derivatives via calcium-promoted hydrothiolation of allenoates is described. Employing diverse allenoates, and amines, a library of α-substituted alkenes is obtained with great regioselectivity and good to high yields. The reaction proceeds through the...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
08 December 2022
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| In: |
ChemistrySelect
Year: 2022, Jahrgang: 7, Heft: 46, Pages: 1-6 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.202203372 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/slct.202203372 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.202203372 
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| Verfasserangaben: | Aida Abdi, S. Sina Hosseini, Ali Nikbakht, Hamid Reza Bijanzadeh, Frank Rominger, Saeed Balalaie |
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| 520 | |a An approach to synthesize α-substituted alkene derivatives via calcium-promoted hydrothiolation of allenoates is described. Employing diverse allenoates, and amines, a library of α-substituted alkenes is obtained with great regioselectivity and good to high yields. The reaction proceeds through the nucleophilic addition of in-situ generated dithiocarbamates to allenoates in a rapid mild method using an eco-friendly metal promoter. | ||
| 650 | 4 | |a allenoates | |
| 650 | 4 | |a dithiocarbamate | |
| 650 | 4 | |a hydrothiolation | |
| 650 | 4 | |a regioselective reaction | |
| 650 | 4 | |a three-component reaction | |
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