Determination of the conformation of the key intermediate in an enantioselective palladium-catalyzed allylic substitution from residual dipolar couplings
Hide and seek! The reactive intermediate in the title reaction has eluded conventional structure determination for years. With the help of residual dipolar couplings the conformation in solution could be determined (see picture). The sensitive intermediate was aligned in a liquid-crystalline phase c...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2010
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| In: |
Angewandte Chemie. International edition
Year: 2010, Jahrgang: 49, Heft: 1, Pages: 205-209 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200903649 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200903649 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200903649 
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| Verfasserangaben: | Benjamin Böttcher, Volker Schmidts, Jevgenij A. Raskatov, and Christina M. Thiele |
MARC
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| 245 | 1 | 0 | |a Determination of the conformation of the key intermediate in an enantioselective palladium-catalyzed allylic substitution from residual dipolar couplings |c Benjamin Böttcher, Volker Schmidts, Jevgenij A. Raskatov, and Christina M. Thiele |
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| 520 | |a Hide and seek! The reactive intermediate in the title reaction has eluded conventional structure determination for years. With the help of residual dipolar couplings the conformation in solution could be determined (see picture). The sensitive intermediate was aligned in a liquid-crystalline phase containing poly(γ-benzyl-L-glutamate), and the orientation of the ligands was determined through local order tensors. | ||
| 650 | 4 | |a allylic substitution | |
| 650 | 4 | |a conformational analysis | |
| 650 | 4 | |a enantioselective catalysis | |
| 650 | 4 | |a NMR spectroscopy | |
| 650 | 4 | |a residual dipolar couplings | |
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| 700 | 1 | |a Thiele, Christina M. |e VerfasserIn |4 aut | |
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