Bridging N-aminoisocyanate ligands in heterobimetallic complexes: coupling of zirconium hydrazinediides and transition-metal carbonyls
Reaction of the zirconium complex [Zr(N2TBSNpy)(═NNPh2)(py)] with metal carbonyl complexes yielded the heteronuclear complexes [(N2TBSNpy)(py)Zr{μ-OCNNPh2-1κC:2κ2NO}Mm(CO)n] (M = Cr, Mo, W (m = 1, n = 5), Fe (m = 1, n = 4), Mn (m = 2, n = 9)). The bridging N-aminoisocyanato ligands in the dinuclear...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2010
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| In: |
Organometallics
Year: 2010, Jahrgang: 29, Heft: 1, Pages: 28-31 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om900877c |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om900877c |
| Verfasserangaben: | Thorsten Gehrmann, Julio Lloret Fillol, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Reaction of the zirconium complex [Zr(N2TBSNpy)(═NNPh2)(py)] with metal carbonyl complexes yielded the heteronuclear complexes [(N2TBSNpy)(py)Zr{μ-OCNNPh2-1κC:2κ2NO}Mm(CO)n] (M = Cr, Mo, W (m = 1, n = 5), Fe (m = 1, n = 4), Mn (m = 2, n = 9)). The bridging N-aminoisocyanato ligands in the dinuclear complexes were formed by [2 + 2] cycloaddition of the Zr═NNR2 unit and coordinated CO. | ||
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