Cover Image

A new insight into gold(I)-catalyzed hydration of alkynes: proton transfer

Solvent molecules have a significant impact on the mechanism of the gold(I)-catalyzed hydration of alkynes as they enable an efficient proton transfer step. As an alternative to such a water-assisted proton transfer, the counterion can serve as a proton shuttle. However, it seems likely that solvent...

Full description

Saved in:
Bibliographic Details
Main Authors: Krauter, Caroline M. (Author) , Hashmi, A. Stephen K. (Author) , Pernpointner, Markus (Author)
Format: Article (Journal)
Language:English
Published: 29 July 2010
In: ChemCatChem
Year: 2010, Volume: 2, Issue: 10, Pages: 1226-1230
ISSN:1867-3899
DOI:10.1002/cctc.201000136
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cctc.201000136
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201000136
Get full text
Author Notes:Caroline M. Krauter, A. Stephen K. Hashmi, and Markus Pernpointner

MARC

LEADER 00000caa a2200000 c 4500
001 1837815313
003 DE-627
005 20230710154935.0
007 cr uuu---uuuuu
008 230301s2010 xx |||||o 00| ||eng c
024 7 |a 10.1002/cctc.201000136  |2 doi 
035 |a (DE-627)1837815313 
035 |a (DE-599)KXP1837815313 
035 |a (OCoLC)1389821527 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 29  |2 sdnb 
100 1 |a Krauter, Caroline M.  |e VerfasserIn  |0 (DE-588)1050858417  |0 (DE-627)785204660  |0 (DE-576)405234961  |4 aut 
245 1 2 |a A new insight into gold(I)-catalyzed hydration of alkynes  |b proton transfer  |c Caroline M. Krauter, A. Stephen K. Hashmi, and Markus Pernpointner 
264 1 |c 29 July 2010 
300 |a 5 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 01.03.2023 
520 |a Solvent molecules have a significant impact on the mechanism of the gold(I)-catalyzed hydration of alkynes as they enable an efficient proton transfer step. As an alternative to such a water-assisted proton transfer, the counterion can serve as a proton shuttle. However, it seems likely that solvent molecules play a vital role for the overall reaction mechanism in either case. 
650 4 |a alkynes 
650 4 |a gold 
650 4 |a proton transfer 
650 4 |a solvent effects 
650 4 |a theoretical studies 
700 1 |a Hashmi, A. Stephen K.  |d 1963-  |e VerfasserIn  |0 (DE-588)101199576X  |0 (DE-627)704823926  |0 (DE-576)169176665  |4 aut 
700 1 |a Pernpointner, Markus  |e VerfasserIn  |0 (DE-588)1025310640  |0 (DE-627)722027036  |0 (DE-576)175257906  |4 aut 
773 0 8 |i Enthalten in  |t ChemCatChem  |d Weinheim : Wiley-VCH, 2009  |g 2(2010), 10 vom: Juli, Seite 1226-1230  |h Online-Ressource  |w (DE-627)603484395  |w (DE-600)2501161-3  |w (DE-576)308344928  |x 1867-3899  |7 nnas  |a A new insight into gold(I)-catalyzed hydration of alkynes proton transfer 
773 1 8 |g volume:2  |g year:2010  |g number:10  |g month:07  |g pages:1226-1230  |g extent:5  |a A new insight into gold(I)-catalyzed hydration of alkynes proton transfer 
776 0 8 |i Erscheint auch als  |n Druck-Ausgabe  |a Krauter, Caroline M.  |t New insight into the gold(I) catalyzed hydration of alkynes  |d 2010  |w (DE-627)1630529613  |w (DE-576)375439714 
856 4 0 |u https://doi.org/10.1002/cctc.201000136  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201000136  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20230301 
993 |a Article 
994 |a 2010 
998 |g 1025310640  |a Pernpointner, Markus  |m 1025310640:Pernpointner, Markus  |d 120000  |d 120300  |e 120000PP1025310640  |e 120300PP1025310640  |k 0/120000/  |k 1/120000/120300/  |p 3  |y j 
998 |g 101199576X  |a Hashmi, A. Stephen K.  |m 101199576X:Hashmi, A. Stephen K.  |d 120000  |d 120100  |e 120000PH101199576X  |e 120100PH101199576X  |k 0/120000/  |k 1/120000/120100/  |p 2 
998 |g 1050858417  |a Krauter, Caroline M.  |m 1050858417:Krauter, Caroline M.  |d 700000  |d 708000  |e 700000PK1050858417  |e 708000PK1050858417  |k 0/700000/  |k 1/700000/708000/  |p 1  |x j 
999 |a KXP-PPN1837815313  |e 4281934561 
BIB |a Y 
SER |a journal 
JSO |a {"recId":"1837815313","language":["eng"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Gesehen am 01.03.2023"],"title":[{"title":"A new insight into gold(I)-catalyzed hydration of alkynes","subtitle":"proton transfer","title_sort":"new insight into gold(I)-catalyzed hydration of alkynes"}],"person":[{"display":"Krauter, Caroline M.","roleDisplay":"VerfasserIn","role":"aut","family":"Krauter","given":"Caroline M."},{"family":"Hashmi","given":"A. Stephen K.","roleDisplay":"VerfasserIn","display":"Hashmi, A. Stephen K.","role":"aut"},{"role":"aut","display":"Pernpointner, Markus","roleDisplay":"VerfasserIn","given":"Markus","family":"Pernpointner"}],"relHost":[{"title":[{"title_sort":"ChemCatChem","subtitle":"the European Society Journal for Catalysis","title":"ChemCatChem"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"disp":"A new insight into gold(I)-catalyzed hydration of alkynes proton transferChemCatChem","note":["Gesehen am 5. November 2022"],"recId":"603484395","language":["eng"],"pubHistory":["1.2009 -"],"part":{"issue":"10","pages":"1226-1230","year":"2010","extent":"5","volume":"2","text":"2(2010), 10 vom: Juli, Seite 1226-1230"},"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"2009-","dateIssuedKey":"2009","publisher":"Wiley-VCH"}],"id":{"issn":["1867-3899"],"zdb":["2501161-3"],"eki":["603484395"],"doi":["10.1002/(ISSN)1867-3899"]},"physDesc":[{"extent":"Online-Ressource"}]}],"physDesc":[{"extent":"5 S."}],"id":{"doi":["10.1002/cctc.201000136"],"eki":["1837815313"]},"origin":[{"dateIssuedDisp":"29 July 2010","dateIssuedKey":"2010"}],"name":{"displayForm":["Caroline M. Krauter, A. Stephen K. Hashmi, and Markus Pernpointner"]}} 
SRT |a KRAUTERCARNEWINSIGHT2920 

Similar Items