A new insight into gold(I)-catalyzed hydration of alkynes: proton transfer
Solvent molecules have a significant impact on the mechanism of the gold(I)-catalyzed hydration of alkynes as they enable an efficient proton transfer step. As an alternative to such a water-assisted proton transfer, the counterion can serve as a proton shuttle. However, it seems likely that solvent...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
29 July 2010
|
| In: |
ChemCatChem
Year: 2010, Volume: 2, Issue: 10, Pages: 1226-1230 |
| ISSN: | 1867-3899 |
| DOI: | 10.1002/cctc.201000136 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cctc.201000136 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201000136 
|
| Author Notes: | Caroline M. Krauter, A. Stephen K. Hashmi, and Markus Pernpointner |
| Summary: | Solvent molecules have a significant impact on the mechanism of the gold(I)-catalyzed hydration of alkynes as they enable an efficient proton transfer step. As an alternative to such a water-assisted proton transfer, the counterion can serve as a proton shuttle. However, it seems likely that solvent molecules play a vital role for the overall reaction mechanism in either case. |
|---|---|
| Item Description: | Gesehen am 01.03.2023 |
| Physical Description: | Online Resource |
| ISSN: | 1867-3899 |
| DOI: | 10.1002/cctc.201000136 |