Stoichiometric reductive C-N bond formation of arylgold(III) complexes with N-nucleophiles
The reductive formation of substituted anilines from amines and three well-defined aryl- gold(III) complexes, i.e., dichloro(2,6-lutidine)phen- ylgold(III) (2), dichloro(2,6-lutidine)-p-tolylgold(III) (3), and chlorobis(triphenylphosphine)phenylgold(III) chloride (4) was studied. The reaction is sto...
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| Hauptverfasser: | , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
16 November 2010
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| In: |
Advanced synthesis & catalysis
Year: 2010, Jahrgang: 352, Heft: 17, Pages: 2993-3000 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000598 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000598 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000598 
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| Verfasserangaben: | Séverine Lavy, Jeremie J. Miller, Marek Pažický, Anne-Sophie Rodrigues, Frank Rominger, Christoph Jäkel, Daniel Serra, Nikolai Vinokurov, and Michael Limbach |
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| 245 | 1 | 0 | |a Stoichiometric reductive C-N bond formation of arylgold(III) complexes with N-nucleophiles |c Séverine Lavy, Jeremie J. Miller, Marek Pažický, Anne-Sophie Rodrigues, Frank Rominger, Christoph Jäkel, Daniel Serra, Nikolai Vinokurov, and Michael Limbach |
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| 520 | |a The reductive formation of substituted anilines from amines and three well-defined aryl- gold(III) complexes, i.e., dichloro(2,6-lutidine)phen- ylgold(III) (2), dichloro(2,6-lutidine)-p-tolylgold(III) (3), and chlorobis(triphenylphosphine)phenylgold(III) chloride (4) was studied. The reaction is stoichiometric in gold and represents a key step of a potential gold-catalyzed intermolecular amination reaction of arenes. It proceeds smoothly with a broad range of N-nucleophiles in the presence of sodium acetate (NaOAc) and enables the selective formation of N-substituted anilines in good yields. A mechanistic pathway is proposed and discussed as well. | ||
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| 650 | 4 | |a CH activation | |
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| 650 | 4 | |a homogeneous catalysis | |
| 650 | 4 | |a reaction mechanisms | |
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| 700 | 1 | |a Vinokurov, Nikolai |e VerfasserIn |4 aut | |
| 700 | 1 | |a Limbach, Michael |e VerfasserIn |4 aut | |
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