Buchumschlag

Stoichiometric reductive C-N bond formation of arylgold(III) complexes with N-nucleophiles

The reductive formation of substituted anilines from amines and three well-defined aryl- gold(III) complexes, i.e., dichloro(2,6-lutidine)phen- ylgold(III) (2), dichloro(2,6-lutidine)-p-tolylgold(III) (3), and chlorobis(triphenylphosphine)phenylgold(III) chloride (4) was studied. The reaction is sto...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Lavy, Séverine (VerfasserIn) , Miller, Jeremie J. (VerfasserIn) , Pažický, Marek (VerfasserIn) , Rodrigues, Anne-Sophie (VerfasserIn) , Rominger, Frank (VerfasserIn) , Jäkel, Christoph (VerfasserIn) , Serra, Daniel (VerfasserIn) , Vinokurov, Nikolai (VerfasserIn) , Limbach, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 16 November 2010
In: Advanced synthesis & catalysis
Year: 2010, Jahrgang: 352, Heft: 17, Pages: 2993-3000
ISSN:1615-4169
DOI:10.1002/adsc.201000598
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000598
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000598
Volltext
Verfasserangaben:Séverine Lavy, Jeremie J. Miller, Marek Pažický, Anne-Sophie Rodrigues, Frank Rominger, Christoph Jäkel, Daniel Serra, Nikolai Vinokurov, and Michael Limbach
Beschreibung
Zusammenfassung:The reductive formation of substituted anilines from amines and three well-defined aryl- gold(III) complexes, i.e., dichloro(2,6-lutidine)phen- ylgold(III) (2), dichloro(2,6-lutidine)-p-tolylgold(III) (3), and chlorobis(triphenylphosphine)phenylgold(III) chloride (4) was studied. The reaction is stoichiometric in gold and represents a key step of a potential gold-catalyzed intermolecular amination reaction of arenes. It proceeds smoothly with a broad range of N-nucleophiles in the presence of sodium acetate (NaOAc) and enables the selective formation of N-substituted anilines in good yields. A mechanistic pathway is proposed and discussed as well.
Beschreibung:Gesehen am 10.03.2023
Beschreibung:Online Resource
ISSN:1615-4169
DOI:10.1002/adsc.201000598

Ähnliche Einträge